Picture used by permission of IMM.org

 Introduction to  Nanotechnology

Picture used by permission of IMM.org

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Current Methods of Fabrication and Design



          This section outlines many forms of current technology.  They are not all considered to be forms of  nanotechnology, but are provided in order to give the reader an understanding of current developments and where nanotechnology will fit in.   

 

Lithography
          Current technology using top-down fabrication techniques has many steps, but the most precise step involves a stream of particles or energy which is used to etch the surface of a device into a certain pattern.  This smallest step which determines the smallest component of a design is referred to as the "critical dimension."  Currently Optical Lithography is still the leading operation used, and involves a focused beam of light produced by Krypton-Fluoride (KrF).  It has been found that the size of the features that can be etched into the surface of the device is limited most significantly by the wavelength of the light being used.  KrF has a wavelength of 248 nanometers and can produce a smallest dimension of around 250 nm, basically the same size as the wavelength.  Other possible light emission sources would be Argon Fluoride (ArF) with a wavelength of 193nm, Fluoride Gas (F2) with a wavelength of 157nm, and Argon Gas(Ar2) with a wavelength of 126 nm.  

          It was expected long ago that optical lithography would hit some physical boundary and that it would no longer be developed for smaller and even smaller applications.  For this reason several alternate possibilities have been researched, but none of them are being used for mainstream manufacturing until optical lithography hits that wall.  It will always be easier for companies to improve and modify their current machinery rather than investing in a whole new technology.  These new technologies are E-beam lithography  (which utilizes a beam of electrons), X-ray lithography (using x-rays), Extreme Ultraviolet Lithography (similar to x-ray but renamed), and Ion Beam Lithography.

** All information in this box was gathered from a slide presentation by Dr. R. J. Trew of Virginia Tech's ECE department as part of the 2001 MicrOn lecture series. **

 

Molecular Design and Advancements
            In order to approach nanoproduction from a bottom-up approach, there are several developmental goals which must be accomplished.  First, we must be able to pick up and place individual atoms in a pattern.  This was done first in the IBM labs in 1989 and was quickly followed by other scientists around the world. However, these first atoms were noble-gases, the group of atoms that are non-reactive and are not be attracted to each other.  Real devices would be made of atoms that would be attracted and would bond together. I am not sure how far they have gotten in actually constructing molecules but I'm sure advancements are still being made in this direction.  
          The other task being accomplished is the design of what molecules and structures would be useful tools.  With the increasingly capable computers that are available, a very complex model such as the interaction of molecules can modeled and predicted.  The decades of hard work by physicists is paying off in that respect because we have numerical models for basically every way that atoms interact, both classically and in the quantum mechanics model.  Many websites on the Links page showcase these designs, but the producer and forerunner in this area is the Institute for Molecular Manufacturing (IMM).

 

Self Assembly
          The use of self-assembly methods is another way of producing nano-thickness devices, utilizing the structure and properties of nature.  This is a hopeful area in further development because it does not require any multi-million dollar equipment.  In the particular method I learned in lab this semester, called Ionically Self-Assembled Monolayers (ISAM), certain polymer solutions are produced and then glass slides are dipped from one beaker into another and back and forth.  The glass has a negative charge to it and will therefore attract ions from the positive ion solution.  Within a period of three minutes (wow!), no more polymers are attaching to the surface and the slide can be rinsed and placed into the bath of negative ions.  Thus a large number of layers can be deposited onto a slide.  This approach has already been used to create flexible diodes and even solar cells, although about a magnitude of efficiency behind the current silicon technology.
         Other techniques involve the creation of nanotubes, or elongated Bucky Balls, and then place additional conductive ions within them.  This method is currently being developed to create nano-transistors,